I think Neuro… was a bit closer to confirming what I was asking.
We were talking about synthesis architecture, and what makes a, “voice,” ie a true polyphonic synth will have independent oscillator, filter, amp and envelope generator boards for each voice…
Therefore, a sample of a polyphonic synth chord, is just a sample of the chord, and loses polyphony if played monophonically.
On an accoustic instrument, when you record a guitar chord - a harmony of several notes, you wind up with a sample. That sample routes into the mixer, etc, etc.
In music theory, the individual, “voices,” that make up a chord, are actually notes. However, chords can have different voicings, “inversions, add_9, minor 7, sus4, etc,” When you record them, you get an audio sample, and not a voice… 
But my question was really weird, and limited in scope to synthesis architecture… and sampling architecture, and if the sample, in a sampler, was a polyphonic voice.
In the XNRI, the sample can be played polyphonically, but you get 1 voice a note. Regardless of whether the sampled sound was originally played mono or polyphonically on a synth, or whether a mono synth has been sampled a dozen times, and had the multiple samples rendered to one chunk of audio. The chuck of audio is just a sample…